Download Carbocation chemistry: applications in organic synthesis by Jie Jack Li PDF

By Jie Jack Li

Carbocation chemistry is not just basic to the development of natural chemistry, it additionally has came upon frequent functions in natural synthesis. it's not an exaggeration to claim that carbocation chemistry is a part of the root of natural chemistry. Carbocation Chemistry: functions in natural Synthesis presents a wide ranging view of carbocation chemistry with an emphasis on artificial functions.

This e-book is a useful software for natural, medicinal and analytical chemists, together with these operating in biochemistry in addition to the petroleum, plastics and pharmaceutical industries. it's also appropriate for higher point undergraduates and graduates in natural chemistry, biochemistry and medicinal chemistry.

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47 Nucleophilic Aliphatic Substitution anthryl OH O O P O OH NH2 N N 82 82 (10 mol%) 83 (30 mol%) O HN OH + O 83 anthryl OPMB O HN 0°C, CHCl3 80% yield, 94% ee OPMB N H 84 N H 85 O HN Steps O NMe N N H H O O (+)-Gliocladin C (86) The combined catalyst of a chiral primary amine and phosphoric acid 82 has been demonstrated to be an efficient system to α-alkylation of aldehydes with 3-hydroxyoxindole 84. 29 Indium(III) salts are unique because, as a Lewis acid, it is compatible with water and amines.

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