By Walsh J.L.
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Extra info for Boundary values of an analytic function and the Tchebycheff method of approximation
Consider the luminol (5-amino-2,3-dihydro-1,4-phthalazinedione) chemiluminescent reaction (R = NH2) shown in Scheme 1. This chemiluminescent reaction is generally carried out in alkaline solutions by the addition of hydrogen peroxide in the presence of an ion such as Fe2+, which generates hydroxyl radical. The mechanism is complicated and leads to destruction of the luminol starting material, with the emitter, the excited phthalate, completely different than the starting material. One can generate chemiluminescence in an electrochemical cell, for example by generating peroxide by the reduction of oxygen or oxidizing luminol [6,7].
M. ; Wiley: New York, 1971; Vol. 1, Part IIB, p. 257. 20. A. Trans. NY Acad. Sci. Ser. II, 1969, 31, 571. 21. Zweig, A. Adv. Photochem. 1968, 6, 425. 22. I. J. Am. Chem. Soc. 1964, 86, 3179. 23. J. J. Am. Chem. Soc. 1968, 90, 6284. 24. M. Science. 1964, 145, 808. 25. A. J. Am. Chem. Soc. 1964, 86, 5350. 26. J. J. Am. Chem. Soc. 1965, 87 139. 27. M. US Patent 3,654,525, April 4, 1972. 28. E. US Patent 3,319,132, May 9, 1967. 29. J. J. Am. Chem. Soc. 1969, 91, 209. 30. A. J. Chem. Phys. 1965, 43, 2654.
Electron Transfer and Spin Up-Conversion Processes Andrzej Kapturkiewicz 163 5. Coreactants Wujian Miao and Jai-Pil Choi 213 6. Organic ECL Systems Samuel P. Forry and R. Mark Wightman 273 7. Metal Chelate Systems Mark M. Richter 321 8. Clinical and Biological Applications of ECL Jeff D. Debad, Eli N. Glezer, Jonathan K. Leland, George B. Sigal, and Jacob Wohlstadter 359 9. Analytical Applications: Flow Injection, Liquid Chromatography, and Capillary Electrophoresis Neil D. Danielson 397 Page vi 10.