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By R. Přibil, R. Belcher, H. Freiser

Analytical purposes of EDTA and similar Compounds examines the analytical purposes of ethylenediaminetetra-acetic acid (EDTA) and similar compounds. This publication additionally considers the “passive” function of those elements, that's, their screening (masking) homes, which vastly increase the selectivity of the reactions in universal use.
This textual content comprises six chapters geared up into sections. the 1st half offers with the makes use of of EDTA and its derivatives in a few fields of chemical research. After supplying an outline of the heritage at the back of the improvement of EDTA as an analytical reagent, this ebook discusses to the character of equilibria of complexes and the equipment utilized in their research. the subsequent bankruptcy is devoted to the reactions of “classical” gravimetric research, together with the precipitation reactions via natural reagents. The bankruptcy on colorimetry contains a part on “colored complexing agents,” that are used additionally in colorimetric determinations of a few parts. this article concludes by way of comparing using EDTA as a overlaying agent in colorimetry.
This publication should be of curiosity to scholars and practitioners operating in analytical chemistry and comparable disciplines, together with polarography, chromatography, electrophoresis, flame photometry, and qualitative research.

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2H2O. 4H20, B a 2 Y . 5H20. 3H2O, N a C o Y . 4 H 2 0 , K C o Y . 2H2O, R b C o Y . 2H2O, CsCoY . 2H2O, Mg[CoY]2l2. H2O, Ca(CoY)2 . 9H2O, C o ( N H 3 ) 6 [ C o Y ] 3 . 6H2O, m[Co(en)2(N02)2] [CoY], irfl/2^[Co(en)2Cl2] [CoY]. These are rather unstable salts because the C o Y " ion is a strong oxidizing agent. On prolonged heating concentrated alkahne C o Y " solution gives ofi* a formaldehyde smell and Co"[CoY]2. IOH2O crystals form on cold storage. 3H20 and the yellow N a V Y . 4H2O which had a metaUic sheen and gave afterwards a gray modification.

2 4 9 , 1 1 3 ( 1 9 4 2 ) . 4 8 . BRWÍTZINGER, H . , THIELE, H . and MÍÍLLER, U . , Z . anorg. chem. 2 5 1 , 2 8 5 ( 1 9 4 3 ) . 4 9 . B R n ^ z n i G E R , H . , Z . anorg. Chem. 256, 6 5 ( 1 9 4 8 ) . 5 0 . SCHWARZENBACH, G . , Helv. chim. acta 3 2 , 8 3 9 ( 1 9 4 9 ) . 51. 52. 53. 54. SCHWARZENBACH, G . and SCHWARZENBACH, G . and SCHWARZENBACH, G . and BRU-, K . and KRUMHOLZ, SANDERA, J . , Helv. chim. acta 3 1 , 4 5 9 ( 1 9 4 8 ) . BIEDERMANN, W . , Helv. chim. acta 3 1 , 4 5 9 ( 1 9 4 8 ) .

And MARTELL, A . , / . Am. Chem. Soc. 7 4 , 5 0 5 7 ( 1 9 5 2 ) . 3 9 . , COURTNEY, R . C . and MARTELL, A. , / . Am. Chem. Soc. 7 5 , 2 1 8 5 ( 1 9 5 3 ) . 4 0 . TOREN, P . E. and KOLTHOFF, I . , / . Am, Chem. Soc. 7 7 , 2 0 6 1 ( 1 9 5 5 ) . 4 1 . Brit. Patent 4 9 6 , 7 8 1 . 4 2 . U . S . Patent 2 , 4 0 7 , 6 4 5 . 4 3 . U . S . Patent 2 , 1 0 3 , 5 0 5 . 4 4 . SCHWARZENBACH, G . and ACKERMANN, H . , Hel^. chim. acta 3 0 , 1 7 9 9 ( 1 9 4 7 ) . 4 5 . CHAPMAN, D . , / . Chem. Soc. 1 9 5 5 , 1 7 6 6 .

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